キラル八面体型金属錯体のCDの起源の新展開

書誌事項

タイトル別名
  • New Development on the Origin of Circular Dichrosim for Chiral Octahedral Metal Complexes
  • New Development on the Origin of Circular Dichroism for Chiral Octahedral Metal Complexes

抄録

Time-dependent density functional theory has been successfully applied to analyze circular dichroism spectra of Δ- or Λ- octahedral metal complexes with bidentate ligands containing both s- and p-orbitals. Rotatory strengths associated with electronic transitions not only d-d transition but also ligand to metal charge transfer (LMCT) and π-π* transitions can be interpreted in terms of transition moments for excitations of metal complexes containing ligand moieties within a qualitative framework.

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詳細情報 詳細情報について

  • CRID
    1390001205297512960
  • NII論文ID
    130000322472
  • DOI
    10.4019/bjscc.55.78
  • ISSN
    18831737
    18826954
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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