過酸化物の分子軌道とＯ‐Ｏ開裂反応

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タイトル別名
  • Molecular Orbitals and O-O Cleavage of Peroxides
  • カサンカブツ ノ ブンシ キドウ ト O O カイレツ ハンノウ

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The reaction mechanisms of the O-O cleavage of organic peroxides, hydrogen peroxide, hydroperoxides, dialkyl peroxides, peracids, peroxyesters, and diacyl peroxides, have been explained on the basis of their HOMO and LUMO and on the basis of the potential surfaces along the reaction paths.<BR>The discussion covers the electronic structure and conformation of the peroxides, the characteristics of HOMO and LUMO of the peroxides, the reaction with nucleophiles and with electrophiles, homolytic decomposition process, radical-induced decomposition, and the electronic structure of the radicals produced from the O-O cleavage.

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