Molecular Orbitals and O-O Cleavage of Peroxides
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- KIKUCHI Osamu
- Department of Chemistry, The University of Tsukuba
Bibliographic Information
- Other Title
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- 過酸化物の分子軌道とO‐O開裂反応
- カサンカブツ ノ ブンシ キドウ ト O O カイレツ ハンノウ
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Abstract
The reaction mechanisms of the O-O cleavage of organic peroxides, hydrogen peroxide, hydroperoxides, dialkyl peroxides, peracids, peroxyesters, and diacyl peroxides, have been explained on the basis of their HOMO and LUMO and on the basis of the potential surfaces along the reaction paths.<BR>The discussion covers the electronic structure and conformation of the peroxides, the characteristics of HOMO and LUMO of the peroxides, the reaction with nucleophiles and with electrophiles, homolytic decomposition process, radical-induced decomposition, and the electronic structure of the radicals produced from the O-O cleavage.
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 37 (8), 678-688, 1979
The Society of Synthetic Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205311586688
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- NII Article ID
- 130000924008
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- NII Book ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 2061792
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed