書誌事項
- タイトル別名
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- Study of Photo-oxidation with Molecular Oxygen
- ブンシジョウ サンソ オ リヨウスル ヒカリ サンカ ハンノウ ノ カイハツ
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Molecular oxygen has recently received much attention, since it is photosynthesized by plants and is an effective oxidant of larger atom efficiency than that of other oxidants. In the course of our study of photo-oxidation, we have found that alcohols and methyl group at aromatic nucleus were oxidized directly to the corresponding carboxylic acids in the presence of catalytic bromine sources, such as lithium bromide, bromine, and hydrobromic acid, in an oxygen atmosphere under irradiation of UV or VIS. This new oxidation reaction is interesting in keeping with the notion of Green Chemistry due to non-use of heavy metals, waste reduction, use of molecular oxygen, and inexpensive acquisition of reagents. Herein, we report our study on the generality of this aerobic photo-oxidation in detail.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 66 (8), 748-756, 2008
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205313138304
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- NII論文ID
- 10024278061
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 9619059
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可