分子触媒の開発・応用・機構解明—ドナー・アクセプター2官能性触媒の展開—

DOI Web Site Web Site 被引用文献8件 参考文献53件

書誌事項

タイトル別名
  • Donor-Acceptor Bifunctional Molecular Catalyst: Its Development, Application, and Analysis
  • 分子触媒の開発・応用・機構解明 : ドナー・アクセプター2官能性触媒の展開
  • ブンシ ショクバイ ノ カイハツ ・ オウヨウ ・ キコウ カイメイ : ドナー ・ アクセプター 2 カンノウセイ ショクバイ ノ テンカイ

この論文をさがす

抄録

De novo development of molecular catalyst (MC) for a targeted ideal reaction is challenging and requires deep understanding of chemistry. Irrespective of the how and why for the finding of high performance MC realizing high reactivity, turnover frequency, selectivity, and productivity, the mechanism should be pursued because it offers a great source of creativity. A detailed mechanistic study of Oguni asymmetric reaction catalyzed by DAIB-Zn complex (DAIB: 3-exo-dimethylaminoisoborneol) has established a new leading concept, that is “Donor-Acceptor Bifunctional Catalyst (DACat),” for the design of a MC. The concept has been categorized into four by two parameters: i) intramolecular (Intramol) or intermolecular (Intermol) and ii) metathesis (M)- or redox (R)-type reaction. The four concepts have realized a new type of MCs including asymmetric hydrogenation of ketones, allyloxy bond cleaving reaction, and asymmetric dehydrative allylation. This account overviews the results obtained in our group.

収録刊行物

被引用文献 (8)*注記

もっと見る

参考文献 (53)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ