Photochemical Mono-silylation of C60 with Silacyclopropane
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- Nakahodo Tsukasa
- Univ. of Tsukuba
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- Nagatsuka Junko
- Univ. of Tsukuba
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- Sugitani Sachie
- Univ. of Tsukuba
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- Kako Masahiro
- Univ. of Electro-Communications
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- Wakahara Takatsugu
- Univ. of Tsukuba
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- Maeda Yutaka
- Tokyo Gakugei univ.
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- Tsuchiya Takahiro
- Univ. of Tsukuba
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- Akasaka Takeshi
- Univ. of Tsukuba
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- Sasaki Yoshiko
- Tohoku Univ.
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- Itoh Osamu
- Tohoku Univ.
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- Kobayashi Kaoru
- IMS
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- Nagase Shigeru
- IMS
Bibliographic Information
- Other Title
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- シラシクロプロパンによるC60の光ケイ素化
Description
In this presentation, we report the photo-chemical reaction of C60 with some silacyclopropanes. C60 reacts with silacyclopropane upon photo-irradiation. In some case, the different major products were observed by the MALDI-TOF MASS spectra measurement. Under the condition of over 400 nm light irradiation, silacyclopropane adducts were obtained as major product. On the other hand, silylene adducts were observed as major product when the shorter wavelength light ( < 400 nm ) was applied for the reaction.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 55 (0), 55-55, 2005
The Society of Physical Organic Chemistry, Japan
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Details 詳細情報について
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- CRID
- 1390001205554227968
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- NII Article ID
- 130004646390
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed
