The Polymerization of Methyl Methacrylate Using Cu(II) Benzamidinate Complexes

  • Shibayama Koichi
    Minase Research Laboratories, R&D Institute, High Performance Plastics Company, Sekisui Chemical Co., Ltd. Graduate School of Science and Technology, Kumamoto University

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タイトル別名
  • Polymerization of Methyl Methacrylate Using Cu 2 Benzamidinate Complexes

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The polymerization of methyl methacrylate (MMA) by Cu(II) amidinate complexes in combination with alkyl aluminum complexes is reported. The preferred alkylating agent is methylaluminoxane (MAO) in terms of improved yield and catalyst activity. Mechanistic studies indicate that the active species is a copper(I) complex.

収録刊行物

  • Polymer Journal

    Polymer Journal 35 (9), 711-713, 2003

    The Society of Polymer Science, Japan

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