A Mechano-Chemical Synthesis of Silver-Ion Conductive Materials in the System Agl-Ag2WO4-Part 2, Vitrification Process by the Ball Milling-
-
- Machida Nobuya
- Department of Chemistry, Konan University
-
- Tomei Naoko
- Department of Chemistry, Konan University
-
- Shigematsu Toshihiko
- Department of Chemistry, Konan University
Bibliographic Information
- Other Title
-
- メカニカルミリング法によるAgI‐Ag2WO4系銀イオン伝導性材料の合成―その2.ミリングによる非晶質化反応過程―
- メカニカルミリングホウ ニ ヨル AgI Ag2WO4ケイギン イオン デンドウセイ ザイリョウ ノ ゴウセイ ソノ 2 ミリング ニ ヨル ヒショウシツカ ハンノウ カテイ
- Part 2, Vitrification Process by the Ball Milling
- その2.ミリングによる非晶質化反応過程
Search this article
Abstract
Vitrification process induced by a ball milling was investigated for silver-ion-conducting materials in the system AgI-Ag2WO4. The amorphous materials were obtained over the wide composition range of 30 to 70mol%AgI content. The silver-ion conductivities of a ball-milled sample showed the maximum at a milling time at which the sample was composed of an amorphous phase and a-Ag2WO4 crystalline phase. This result suggested that the amorphous phase was containing a large amount of AgI content and the amorphous phase was a high ion conductive phase. The maximum conductivity 4.8×10-2 Scm-1 at 298 K was observed for the 70AgI⋅0Ag2WO4(mol%) sample ball-milled for 20 h. This conductivity was higher than that of the completely amorphous sample with the same composition.
Journal
-
- Journal of the Japan Society of Powder and Powder Metallurgy
-
Journal of the Japan Society of Powder and Powder Metallurgy 51 (9), 662-667, 2004
Japan Society of Powder and Powder Metallurgy
- Tweet
Details 詳細情報について
-
- CRID
- 1390001206307347200
-
- NII Article ID
- 130000831468
-
- NII Book ID
- AN00222724
-
- ISSN
- 18809014
- 05328799
-
- NDL BIB ID
- 7110092
-
- Text Lang
- ja
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed