多孔性金属錯体による分子分離技術の新展開

  • 細野 暢彦
    京都大学 物質-細胞統合システム拠点
  • 日下 心平
    京都大学 物質-細胞統合システム拠点
  • 松田 亮太郎
    京都大学 物質-細胞統合システム拠点 名古屋大学大学院 工学研究科 科学技術振興機構(JST)さきがけ

書誌事項

タイトル別名
  • New Developments of Molecular Separation Technology by Porous Coordination Compounds
  • タコウセイ キンゾク サクタイ ニ ヨル ブンシ ブンリ ギジュツ ノ シン テンカイ

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抄録

Technological needs for gas separation is being increased to date because of the environment and energy crisis of the current world. Porous coordination compounds (PCCs) or metal organic frameworks (MOFs) have recently attracted significant attention due to their potential in gas capture/separation applications. Their porous structures (e.g. pore and window sizes) as well as affinities to the gas molecules can be designed by the selection of chemical constituents (organic ligands and metal ions), which allow a variety of PCCs used for separations of various molecules in gas or liquid phase. In gas separation applications, PCCs have been used not only as adsorbents but also as solid membranes. Recently, PCC/polymer hybrid is emerging as a new strategy to realize PCC–based membranes with a sort of flexibility and processability. In this review, we highlight gas separation technique using PCCs and introduce emerging approaches towards PCC–based flexible membranes.

収録刊行物

  • 膜 41 (4), 160-164, 2016

    日本膜学会

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