高分子固体電界質上に蒸着したステアリン酸アルミニウム薄膜へのリチウムイオンの拡散

DOI

書誌事項

タイトル別名
  • Diffusion of Li+ Ions into Multilayers of Aluminum Stearate Deposited on Polymeric Solid Electrolytes.

抄録

The diffusion of Li+ ions from a polymeric Solid electrolyte (PSE) into multilaycrs of aluminum Stearate dimer (SA-Al (di)) was investigated at a D. C. voltage of 10mV. The multilayer was deposited on the PSE in vacuum at 2.0 ×10-5 Torr. The PSE consists of LiClO4, Poly (ethylene oxide) (PEO) and poly (vinyl acetate) (PVAc). DiffuSion of dissociated Li+ in PSE substrate into the multilayers was observed. The diffusion was larger when the voltage was Supphed at 4°C than at-10°C or 40°C. The Li+seemes to bind again with ClO-4 or to coordinate to the oxygen atoms of the SA-AR (di) in the multilayers. The above results can be applied for the fabrication of high quality organicinorganic layered superlattices by means of doping inorganic materials into the organic multilayers.

収録刊行物

  • 高分子論文集

    高分子論文集 51 (12), 778-782, 1994

    公益社団法人 高分子学会

キーワード

詳細情報 詳細情報について

  • CRID
    1390001206521858816
  • NII論文ID
    130004034975
  • DOI
    10.1295/koron.51.778
  • ISSN
    18815685
    03862186
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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