不飽和二塩基酸誘導体の合成と重合に関する研究 第24報 α‐メチルスチレン,アクリロニトリルとN‐フェニルマレイミド,及びN‐p‐クロロフェニルマレイミド三元共重合体の合成と熱的性質

書誌事項

タイトル別名
  • Studies on synthesis and polymerization of unsaturated dibasic acid derivatives. XXIV. Radical terpolymerization of .ALPHA.-methylstyrene and acrylonitrile with N-phenyl- and N-p-chlorophenylmaleimides and thermal properties of the terpolymers.

抄録

Terpolymerizations of α-methylstyrene (MS) and acrylonitrile (AN) with N-phenylmaleimide (PMI) or N-p- chlorophenyhnaleimide (CPMI) were carried out by dropping a solution of different amounts of PMI or CPMI in cyclohexanone into the MS-AN copolymerization system in the presence of radical initiator at 80°C. Five terpolymers containing about 3 to 17 mol% of PMI or CPMI units were obtained. The thermal behavior of the terpolymers was examined by TG and DSC measurements. In both series of terpolymers, the glass transition and initial thermal decomposition temperatures and softening point increased markedly with increasing PMI or CPMI composition in the terpolymers.

収録刊行物

  • 高分子論文集

    高分子論文集 47 (8), 683-689, 1990

    公益社団法人 高分子学会

被引用文献 (2)*注記

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詳細情報 詳細情報について

  • CRID
    1390001206522501504
  • NII論文ID
    130004034679
  • DOI
    10.1295/koron.47.683
  • ISSN
    18815685
    03862186
    http://id.crossref.org/issn/03862186
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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