ポリ（ふっ化ビニリデン）の放射線照射効果　ＶＩＩＩ　　トリメリット酸トリアリルを添加し放射線橋かけしたポリ（ふっ化ビニリデン）の機械的性質

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タイトル別名
  • Mechanical Properties of Poly (vinylidene fluoride) Crosslinked by γ-Ray Irradiation in the Presence of Triallyl Trimellitate
  • トリメリットサン トリアリル オ テンカシタ ホウシャセン バシ カ ケシタ

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説明

Accelerating effect of triallyl trimellitate (TATM) on the radiation-induced crosslinking of poly (vinylidene fluoride) (PVdF) and the mechanical properties of the crosslinked PVdF have been ivestigated. Gel fraction, swelling ratio, and stress-strain curves at ambient temperature, 100°, 150°, and 180°C were measured. TATM was found to be an efficient sensitizer for radiation-induced crosslinking of PVdF. No appreciable difference in gel fraction was found between 5% and 10% TATM containing PVdF's crosslinked at the same dose. However, swelling ratio and the stress-strain curves exhibited that the crosslinking density increased with TATM content. Noticeable changes in the mechanical properties with dose were increase in the yield strength and decrease in the elongation at break. The effect of crosslinking in the presence of TATM was clearly observed in 100% modulus at 180°C, near the melting temperature of PVdF.

収録刊行物

  • 高分子論文集

    高分子論文集 34 (7), 515-520, 1977

    公益社団法人 高分子学会

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