書誌事項
- タイトル別名
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- Preparation and Photochemical Properties of Poly (vinylpyridine-co-vinylbipyridine) Pendant [Ru (bpy) <SUB>3</SUB>]<SUP>+2</SUP> Complex
- ビニルピリジン ビニルビピリジン キョウジュウゴウ タイケイ Ru bpy 3
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抄録
Polymer pendant tris (2, 2′-bipyridine) ruthenium (II) type complexes were prepared from the copolymer of 4-vinylpyridine (Vpy) and 4-methyl-4′-vinyl-2, 2′-bipyridine (Vbpy), and from its derivative quaternized with bromoethane. In the reaction of P (Vpy-Vbpy) with cis-Ru (bpy) 2Cl2, the coordination of the Vpy groups occurred at first rapidly, followed by the formation of the [Ru (bpy) 3]2+ type complex by ligand substitution. The photoexcited states of both the polymer pendant complexes ; Ru [P (Vpy-Vbpy)] (bpy) 22+ and Ru [EQ-P (Vpy-Vbpy)] - (bpy) 22+, showed two kinds of lifetime species, the longer lifetime being almost the same as [Ru (bpy) 3]2+ (500-600 ns). The excited state of the Ru [EQ-P (Vpy-Vbpy)] (bpy) 22+ showed remarkably short lifetime of ca. 10ns, which is considered to be due to the heavy atom effect of the bromine.
収録刊行物
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- 高分子論文集
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高分子論文集 41 (5), 311-314, 1984
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390001206523496192
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- NII論文ID
- 130004034185
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- NII書誌ID
- AN00085011
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- ISSN
- 18815685
- 03862186
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- NDL書誌ID
- 2984883
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可