ポリ（１，３－シクロヘキサジエン）のＮＭＲスペクトルの解析

名取 至, 数乗 幸, 山岸 秀之

doi:10.1295/koron.61.197

書誌事項

タイトル別名

NMR Spectra Analysis of Poly (1,3-cyclohexadiene)

説明

The NMR spectra of poly (1, 3-cyclohexadiene) (PCHD) were studied. PCHD was synthesized by living anionic polymerization of 1, 3-cyclohexadiene (1, 3-CHD) with the n-butyllithium (n-BuLi) /N, N, N′, N′-tetramethylethylenediamine (TMEDA) system as an initiator. PCHD has a structure consisting of a main chain formed by1, 2-addition (1, 2-unit) and 1, 4-addition (1, 4-unit). The complicated ¹H and ¹³C NMR spectra of poly (1, 3-cyclohexadiene) (PCHD) were observed. The spectral assignment of 1H NMR spectrum of PCHD with the 1, 2-units and 1, 4-units was determined by two dimensional (2D) and Distortionless Enhancement by Polarization Transfer (DEPT) NMR spectroscopy techniques.

収録刊行物

高分子論文集

高分子論文集 61 (3), 197-199, 2004

公益社団法人高分子学会

キーワード

詳細情報詳細情報について

CRID: 1390001206524097664

NII論文ID: 130004035666

DOI: 10.1295/koron.61.197

ISSN: 18815685; 03862186

本文言語コード: ja

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