X 線は電子のプローブである- 放射光科学と最大エントロピー法による錯体構造化学の革新-

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  • 高田 昌樹
    東北大学国際放射光イノベーション・スマート研究センター

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  • Innovation in Coordination Structural Chemistry by Synchrotron Radiation Science and Maximum Entropy Method

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<p>Since 2002, the structural science via Maximum Entropy Method based on synchrotron radiation(SR) diffraction data has driven an innovation of structural chemistry in Coordination Chemistry at SPring-8. The first successful contribution of the MEM Structural Science was a discovery of the peculiar structure of absorbed gas molecules in the nanopore of coordination polymer. The revealed one-dimensional array structure of absorbed gas molecules with no charge transfer made chemists recognize the power of Synchrotron Radiation as a probe of electrons in materials. The development of the MEM/Rietveld Method is described in terms of absorbed molecular site prediction as well as finding charge transfer among host-guest molecules. The expected role of the Next Generation Synchrotron Radiation facility under construction at Tohoku University Campus is also noted.</p>

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