ジシクロペンタジエンから誘導されるペルフルオロオクチル基含有メタクリレートの合成とその共重合物のぬれ特性

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書誌事項

タイトル別名
  • Synthesis of a Methacrylate Monomer Containing Perfluorooctyl Group Derived from Dicyclopentadiene and the Wetting Property of its Copolymer
  • ジシクロペンタジエン カラ ユウドウサレル ペルフルオロオクチルキ ガンユウ
公開日
1998
DOI
  • 10.5650/jos1996.47.777
公開者
公益社団法人 日本油化学会

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説明

A methacrylate introduced the perfluorooctyl group was synthesised from the 2-(perfluorooctyl) ethanol and dicyclopentadiene. The monomer and 2-(perfluorooctyl) ethyl methacrylate as control were effective for copolymerzation with styrene. Each monomer reactivity ratio were r1=1.35, r2=0.48 and r1=1.22, r2=0.99 (1: styrene) respectively.<BR>Contact angle of water on the coating sample of copolymer with styrene and cured coating sample of unsaturated polyester mixed with the monomer increased as perfluorooctyl group concentration. The former angle increased gradually with perfluorooctyl group concentration, while the latter did rapidly. It supposedly depend on localizing of perfluorooctyl group on the surface because of special properties of fluoro organic compounds.

収録刊行物

  • 日本油化学会誌

    日本油化学会誌 47 (8), 777-782,790, 1998

    公益社団法人 日本油化学会

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