Electrodeposition of Chromium from Chromium (III)

Bibliographic Information

Other Title
  • 塩化クロム(III)六水塩の種々の有機溶媒中からのクロムの電析
  • (III) 六水塩の種々の有機溶媒中からのクロムの電析

Description

The present study has been made to investigate the electrodeposition of chromium from CrCl3⋅6H2O-HCONH2, CrCl3⋅6H2O-HCON (CH3)2, and CrCl3⋅6H2O-(CH3)2SO solutions with additives. The solubility of CrCl3⋅6H2O in the organic solvents and the specific conductance of the solutions were measured, and these values were found to be generally lower than those in aqueous systems. The optimum conditions of the electrolysis in organic solvents were determined. Thin, bright and smooth deposits were obtained from the above conditions with a low cathode current efficiency (less than 30%). Chromium deposition mechanism is discussed in terms of the formation of chromium (III) complex ions in FA, DMF and DMSO solvents.

Journal

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Details 詳細情報について

  • CRID
    1390282679088464256
  • NII Article ID
    130003994531
  • DOI
    10.4139/sfj1950.34.12
  • ISSN
    18843395
    00260614
  • Text Lang
    ja
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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