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Electrodeposition of Chromium from Chromium (III)
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- TSURU Toshiaki
- Department of Industrial Chemistry, Fac. of Eng., Kyushu Sangyo Univ.
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- KOBAYASHI Shigeo
- Department of Industrial Chemistry, Fac. of Eng., Kyushu Sangyo Univ.
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- KUSUHARA Koki
- Graduate School of Kyushu Sangyo Univ.
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- INUI Tadayoshi
- Department of Industrial Chemistry, Fac. of Eng., Kyushu Sangyo Univ.
Bibliographic Information
- Other Title
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- 塩化クロム(III)六水塩の種々の有機溶媒中からのクロムの電析
- (III) 六水塩の種々の有機溶媒中からのクロムの電析
Description
The present study has been made to investigate the electrodeposition of chromium from CrCl3⋅6H2O-HCONH2, CrCl3⋅6H2O-HCON (CH3)2, and CrCl3⋅6H2O-(CH3)2SO solutions with additives. The solubility of CrCl3⋅6H2O in the organic solvents and the specific conductance of the solutions were measured, and these values were found to be generally lower than those in aqueous systems. The optimum conditions of the electrolysis in organic solvents were determined. Thin, bright and smooth deposits were obtained from the above conditions with a low cathode current efficiency (less than 30%). Chromium deposition mechanism is discussed in terms of the formation of chromium (III) complex ions in FA, DMF and DMSO solvents.
Journal
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- Journal of the Metal Finishing Society of Japan
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Journal of the Metal Finishing Society of Japan 34 (1), 12-18, 1983
The Surface Finishing Society of Japan
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Details 詳細情報について
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- CRID
- 1390282679088464256
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- NII Article ID
- 130003994531
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- ISSN
- 18843395
- 00260614
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- Text Lang
- ja
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed