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Effect of polyether linkages on the carboxylation of sodium phenoxide.
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- Sakakibara Tsutomu
- Institute of Chemistry, College of Liberal Arts, Kagoshima University
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- Haraguchi Kazuyo
- Institute of Chemistry, College of Liberal Arts, Kagoshima University
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Description
In the carboxylation of sodium phenoxide under mild conditions, the crown compound or polyethers with three to five ether linkages caused carboxylation to give o- and p-hydroxybenzoic acids, but not ethers with one or two linkages. The chelation of sodium phenoxide with polyethers changed the formation ratio of isomers.
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 53 (1), 279-280, 1980
The Chemical Society of Japan
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Details 詳細情報について
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- CRID
- 1390282679102003840
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- NII Article ID
- 130001988556
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- ISSN
- 13480634
- 00092673
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed