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New Cineromycins and Musacins Obtained by Metabolite Pattern Analysis of Streptomyces griseoviridis FH-S 1832). II. Structure Elucidation.
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- SCHNEIDER ANDREA
- Institut für Organische Chemie, Universität Göttingen
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- SPÄTH JULIA
- Institut für Organische Chemie, Universität Göttingen
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- BREIDING-MACK SABINE
- Institut für Organische Chemie, Universität Göttingen
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- ZEECK AXEL
- Institut für Organische Chemie, Universität Göttingen
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- GRABLEY SUSANNE
- Hans-Knöll-Institut für Naturstoff-Forschung e.V.
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- THIERICKE RALF
- Hans-Knöll-Institut für Naturstoff-Forschung e.V.
Bibliographic Information
- Other Title
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- II. Structure Elucidation
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Description
A detailed analysis of the secondary metabolite pattern produced by Streptomyces griseoviridis (strain FH-S 1832) using a chemical screening method resulted in the detection, isolation and structure elucidation of new 14-membered lactones of the cineromycin B-type [dehydrocineromycin B (5), oxycineromycin B (7), and 2, 3-dihydrocineromycin B (8)], as well as new γ-lactones related to nigrosporalactone and 4, 5-dihydroxy-octa-2, 6-dienoic acid esters named musacins A to F (10, 13-15, 17, 18 and 21). The constitution of these metabolites were deduced from spectroscopic data as well as chemical transformations. The configuration of musacin D (10) was determined by derivatization with chiral acids (Helmchen's method).
Journal
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- The Journal of Antibiotics
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The Journal of Antibiotics 49 (5), 438-446, 1996
JAPAN ANTIBIOTICS RESEARCH ASSOCIATION
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Details 詳細情報について
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- CRID
- 1390282679127602304
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- NII Article ID
- 130003503100
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- COI
- 1:CAS:528:DyaK28Xjt1Gktbo%3D
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- ISSN
- 18811469
- 00218820
- http://id.crossref.org/issn/00218820
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- PubMed
- 8682720
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- JaLC
- Crossref
- PubMed
- CiNii Articles
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- Abstract License Flag
- Disallowed