Chemical modification of carbapenem antibiotics. Versatile methods for displacement of the C-3 sulfur side chain of carbapenems with other thiol groups.

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  • Chemical Modification of Carbapenem Ant
  • VERSATILE METHODS FOR DISPLACEMENT OF THE C-3 SULFUR SIDE CHAIN OF CARBAPENEMS WITH OTHER THIOL GROUPS

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説明

Carbapenem derivatives substituted at the C-3 position were synthesized (1) by treating carbapenem S-oxides with various mercaptans in the presence of a base (Fig. 3), or (2) by alkylating or acylating 3-thiol carbapenems (Fig. 4).

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