Sugar-Sensitive Supramolecular Structures Based on Phenylboronic Acid-Modified Cyclodextrins
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- Nakamura Kiminobu
- Faculty of Pharmaceutical Sciences, Josai University
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- Seki Tomohiro
- Faculty of Pharmaceutical Sciences, Josai University
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- Egawa Yuya
- Faculty of Pharmaceutical Sciences, Josai University
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- Miki Ryotaro
- Faculty of Pharmaceutical Sciences, Josai University
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- Oda Yoshiki
- The Noguchi Institute
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- Yamanoi Takashi
- The Noguchi Institute
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- Seki Toshinobu
- Faculty of Pharmaceutical Sciences, Josai University
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Supramolecular structures were developed from phenylboronic acid-modified cyclodextrins (PBA-CyDs). The intermolecular interaction between the PBA moiety and the CyD cavity was proved using two dimensional (2D)-NMR and powder X-ray diffraction techniques. PBA-α-CyD formed a head-to-tail supramolecular polymer, whereas PBA-β-CyD formed a head-to-head dimer. The supramolecular structures were disintegrated in the presence of sugars owing to the resulting boronate sugar interactions.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 61 (11), 1188-1191, 2013
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390282679154631296
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- NII論文ID
- 130003360911
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- NII書誌ID
- AA00602100
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- COI
- 1:STN:280:DC%2BC3sbhvVCitw%3D%3D
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- ISSN
- 13475223
- 00092363
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- NDL書誌ID
- 024957262
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- PubMed
- 23965519
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可