スルホン酸のガスクロマトグラフィー

DOI NDLデジタルコレクション Web Site Web Site

書誌事項

タイトル別名
  • Gas-liquid chromatographic analysis of sulfonic acids
  • スルホンサン ノ ガス クロマトグラフィー

この論文をさがす

抄録

A method has been presented for the analysis of sulfonic acids and salts by gas-liquid chromatography of their volatile derivatives. The sulfonic acid and salt were converted first to the sulfonyl chloride by reaction with phosphorous pentachloride. Then, without isolation, the sulfonyl chloride was converted to the thiol by reduction with lithium tetrahydridoaluminate hydride. Naphthalenemono- and dithiol isomers were converted to trimethylsilyl derivatives with N, O-bis (trimethylsilyl) acetamide. The thiol derivatives and the trimethylsilyl derivatives were separated on a (1m×3mm) glass column packed with 3% of OV-1 on Chromosorb W DMCS {(80100) mesh}. This method was applied to sodium toluenemono- and disulfonate and sodium naphthalenemono-, di- and trisulfonate and sodium dodecanesulfonate.

収録刊行物

  • 分析化学

    分析化学 28 (7), 410-414, 1979

    公益社団法人 日本分析化学会

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ