- 【Updated on May 12, 2025】 Integration of CiNii Dissertations and CiNii Books into CiNii Research
- Trial version of CiNii Research Knowledge Graph Search feature is available on CiNii Labs
- 【Updated on June 30, 2025】Suspension and deletion of data provided by Nikkei BP
- Regarding the recording of “Research Data” and “Evidence Data”
Oxidation of Phenylhydrazine with Sodium Periodate in the Presence of Primary and Secondary Aliphatic Alcohols -Oxidation Reaction of Phenylhydrazine with Sodium Periodate. II.-
-
- TSUBOI Masaki
- Yonago National College of Technology
-
- NANBARA Isamu
- Present address: Daikin Industries, Ltd.
-
- MATSUMOTO Toshio
- Present address: Takeda Chemical Industyies, Ltd.
-
- MURAKAMI Fumiyasu
- Present address: Asahi Chemical Industry Co., Ltd.
Bibliographic Information
- Other Title
-
- 脂肪族第一級および第二級アルコール存在下での過ヨウ素酸ナトリウムによるフェニルヒドラジンの酸化反応
- Oxidation reaction of phenylhydrazine with sodium periodate. II. Oxidation of phenylhydrazine with sodium periodate in the presence of primary and secondary aliphatic alcohols.
Search this article
Description
Oxidation of phenylhydrazine with aqueous solution of sodium periodate in the presence of eleven kinds of simple aliphatic alcohols was investigated at 40±1°C.1-Phenyl-1, 2, 4triazole(1.0%) was obtained in Me0H and 3, 5-dirnethy1-1-phenyl-1, 2, 4-triazole(0.5%) in EtOH. The new phenylazo-substituted alcohols were also obtained in i-BuOH, i-C5H11OH, 2-pentanol, 4-methyl-1-pentanol and 4-methyl-2-pentanol (Table 1).3, 5-Dimethy1-1phenyl-1, 2, 4-triazole was also obtained by using acetaldehyde phenylhydrazone instead of EtOH under the above reaction conditions and a reaction of acetaldehyde phenylhydrazone with benzoyl peroxide in MeOH gave the same product (Scheme 2). The reaction route leading to each product was conceivably summarized as shown in Schemes 3 and 4.
Journal
-
- NIPPON KAGAKU KAISHI
-
NIPPON KAGAKU KAISHI 1988 (3), 294-298, 1988-03-10
The Chemical Society of Japan
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1390282679366329984
-
- NII Article ID
- 130004158918
-
- ISSN
- 21850925
- 03694577
-
- Data Source
-
- JaLC
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed