Reactions of 3, 4: 9, 10-Perylenetetracarboxylic with Alkylaminest

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  • NAGAO Yukinori
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
  • TANABE Yoriko
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
  • MISONO Takahisa
    Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo

Bibliographic Information

Other Title
  • 3,4:9,10-ペリレンテトラカルボン酸無水物と脂肪族アミンの反応
  • ペリレンカルボン酸誘導体の合成と反応　ＩＩＩ　　３，４：９，１０‐ペリレンテトラカルボン酸無水物と脂肪族アミンの反応

Description

The condensation products of 3, 4: 9, 10-perylenetetracarboxylic dianhydride [1] with amines [4 a-e ](a; ammonia, b; methylamine, c; ethylamine, d; propylamine, e; butylamine) were spectroscopically determined. Under all reaction conditions, N-substituted 3, 4: 9, 10-perylenetetracarboxylic monoanhydride monoimides [2 a-e] (R=H, CH3, CH2CF13, CH2CH2CH3, CH2, - CH2, CH2, CH3, ) were obtained. As the reactions proceed, the yield of [2 a, -e] increased at an initial stage but decreased after reaching a maximum. This maximum yield of[2] was: [2 e]; 50-60%, [2 b]; 40-50%, [2 c]; 60-70%, [2 d]; 65-75%, [2e];80 85%. A long alkyl chain in amines appeared to be favorable for the increased formation of[2]<BR>The kinetics of this reaction were also examined and discussed.

Journal

  • NIPPON KAGAKU KAISHI

    NIPPON KAGAKU KAISHI 1979 (4), 528-534, 1979-04-10

    The Chemical Society of Japan

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