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Stereocontrolled Total Synthesis of (-)-Gleenol Using Claisen Rearrangement of Sterically Congested Dihydropyran
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- Nakazaki Atsuo
- Faculty of Pharmaceutical Sciences, Tokyo University of Science
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- Era Tomohiro
- Faculty of Pharmaceutical Sciences, Tokyo University of Science
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- Kobayashi Susumu
- Faculty of Pharmaceutical Sciences, Tokyo University of Science
Bibliographic Information
- Other Title
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- Stereocontrolled Total Synthesis of (−)-Gleenol Using Claisen Rearrangement of Sterically Congested Dihydropyran
- ChemInform Abstract: Stereocontrolled Total Synthesis of (‐)‐Gleenol Using Claisen Rearrangement of Sterically Congested Dihydropyran.
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Description
A stereocontrolled total synthesis of enantiomerically pure (−)-gleenol using an improved substrate to construct the spiro[4.5]decane through Claisen rearrangement has been achieved. The most striking feature of this synthesis is that the rearrangement of sterically congested dihydropyran, bearing all requisite substituents with proper stereochemistry, afforded the fully functionalized spiro[4.5]decane in a single step.
Journal
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- Chemistry Letters
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Chemistry Letters 37 (7), 770-771, 2008
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679562223232
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- NII Article ID
- 130004425201
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- ISSN
- 13480715
- 15222667
- 03667022
- 09317597
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
- OpenAIRE
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- Abstract License Flag
- Disallowed
