Selective Hydroconversion of <i>n</i>-Heptane over Pd-supported Zeolites and Pd-containing Hybrid Catalyst

DOI Web Site Web Site 3 Citations 31 References
  • Li Xiaohong
    Dept. of Chemical Processes and Environments, Faculty of Environmental Engineering, The University of Kitakyushu
  • Yang Jiani
    Dept. of Chemical Processes and Environments, Faculty of Environmental Engineering, The University of Kitakyushu
  • Liu Zhong-Wen
    Dept. of Chemical Processes and Environments, Faculty of Environmental Engineering, The University of Kitakyushu College of Chemistry and Chemical Engineering, Nanjing University of Technology
  • Asami Kenji
    Dept. of Chemical Processes and Environments, Faculty of Environmental Engineering, The University of Kitakyushu
  • Fujimoto Kaoru
    Dept. of Chemical Processes and Environments, Faculty of Environmental Engineering, The University of Kitakyushu

Bibliographic Information

Other Title
  • Pd担持ゼオライトとハイブリッド触媒を用いる<i>n</i> -ヘプタンの選択的水素化転換
  • Selective Hydroconversion of n-Heptane over Pd-supported Zeolites and Pd-containing Hybrid Catalyst

Search this article

Abstract

Hydroconversion of n-heptane was investigated over Pd-supported H-zeolite and hybrid catalyst consisting of Pd/SiO2 and USY. Highly selective hydrocracking occurred over Pd/ZSM-5 whereas hydroisomerization dominated over Pd/USY and Pd/β. Skeletal isomerization occurred before the cracking reactions. The zeolite used and hydrogen spillover onto the zeolite were important in determining the isomerization selectivity. Experiments over hybrid catalysts suggested that close contact and the balance of metal and acidic sites are crucial in determining the activity and selectivity of isomerization and cracking. A reaction scheme based on the concept of hydrogen spillover was proposed.<br>

Journal

Citations (3)*help

See more

References(31)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top