Sol-gel synthesis of fluorine-doped silica glasses with low SiOH concentrations
-
- MAEHANA Ryohei
- Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University
-
- KUWATANI Shungo
- Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University
-
- KAJIHARA Koichi
- Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University
-
- KANAMURA Kiyoshi
- Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University
Search this article
Abstract
Fluorine-doped monolithic silica glasses with low SiOH concentrations were prepared by a sol–gel method using hydrofluoric acid as a fluorine source. Without employing dehydration of dried gels using halogen-containing gases, or vacuum sintering, the concentration of SiOH groups was reduced to ∼1017 cm−3 (∼1 ppmw), which is comparable to that of synthetic silica glasses mildly dehydrated during their vapor-phase synthesis. The fluorine concentration evaluated from the intensity of the Raman band of SiF groups (∼945 cm−1) was in the order of ∼1020–1021 cm−3.
Journal
-
- Journal of the Ceramic Society of Japan
-
Journal of the Ceramic Society of Japan 119 (1390), 393-396, 2011
The Ceramic Society of Japan
- Tweet
Details 詳細情報について
-
- CRID
- 1390282680264253824
-
- NII Article ID
- 130000784597
-
- NII Book ID
- AA12229489
-
- ISSN
- 13486535
- 18820743
-
- NDL BIB ID
- 11096675
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
-
- Abstract License Flag
- Disallowed