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- 今村 寿一
- 東京工業試験所
書誌事項
- タイトル別名
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- Manufactuaring Process of Aromatic Aldehydes by Liquid Phase Autoxidation
- エキソウ ジドウ サンカホウ ニヨル ホウコウゾク アルデヒド ゴウセイ
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説明
In general, it is difficult to prepare an aromatic aldehyde by the liquid-phase autoxidation of the corresponding toluene derivative because the aldehyde once formed is immediately oxidized to the carboxylic acid. The present author and his co-workers have been trying to prepare an aromatic aldehyde by the autoxidation of the corresponding toluene derivative, and have succeeded in obtaining the aldehyde with a good yield.<BR>Therefore, the author's works on the synthesis of aromatic aldehydes by autoxidation are reviewed in some detail covering the following subjects : synthesis of hydrocarbyloxy benzaldehydes by liquid phase autoxidation of hydrocarbyloxy toluenes in acetic acid in the presence of cobalt acetate, synthesis of substituted benzaldehydes by liquid phase autoxidation of substituted toluenes in acetic acid in the presence of cobalt acetate and sodium bromide.<BR>To clarify the description of the author's works, a brief survey on the industrial routes and use of aromatic aldehydes, especially benzaldehyde, anisaldehyde, and m-phenoxybenzaldehyde, is given. Benzaldehyde is the simplest aromatic aldehyde, anisaldehyde is produced in the highest yield with the author's method and m-phenoxybenzaldehyde is one of the key elements of the insecticides named “synthetic pyrethroides”.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 37 (8), 667-677, 1979
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680287943552
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- NII論文ID
- 130000924002
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 2061795
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可