face-to-face型π－π相互作用を利用した超分子構築
書誌事項
- タイトル別名
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- Supramolecular Assembly Comprised of Face-to-face π/π Interaction
抄録
We here report crystal engineering using face-to-face pi-pi interaction of anthracene moieties. Its interaction energy is estimated about 8 kcal/mol, which is comparative to that of hydrogen bond. First, we examine solvent effect in crystallization of 1,3-diphenyl-2-propanol. When benzene was used as solvent, polymorph was obtained, probably because benzene disturbed the pi-pi interaction between anthracenes. Next, crystalline inclusion host compounds bearing three-fold axis and three anthracene planes are designed and synthesized. It is revealed that those compounds include various guest component.
収録刊行物
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- 基礎有機化学討論会要旨集（基礎有機化学連合討論会予稿集）
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基礎有機化学討論会要旨集（基礎有機化学連合討論会予稿集） 16 (0), 1073-1073, 2002
基礎有機化学会（基礎有機化学連合討論会）
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詳細情報 詳細情報について
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- CRID
- 1390282680531503232
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- NII論文ID
- 130004644613
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- データソース種別
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- JaLC
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可