Reversible addition reaction of La@C<SUB>82</SUB> with cyclopentadiene derivatives
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- Sato Satoru
- TARA center, Univ. of Tsukuba
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- Maeda Yutaka
- Dept. Chem., Tokyo Gakugei Univ.
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- Inada Koji
- Dept. Chem., Tokyo Gakugei Univ.
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- Hasegawa Tadashi
- Dept. Chem., Tokyo Gakugei Univ.
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- Yamada Michio
- TARA center, Univ. of Tsukuba
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- Tsuchiya Takahiro
- TARA center, Univ. of Tsukuba
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- Akasaka Takeshi
- TARA center, Univ. of Tsukuba
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- Kato Tatsuhisa
- Dept. Chem., Jyosai Univ.
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- Mizorogi Naomi
- IMS
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- Nagase Shigeru
- IMS
Bibliographic Information
- Other Title
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- La@C<SUB>82</SUB>とシクロペンタジエン誘導体の可逆付加反応
Description
Endohedral metallofullerenes have attracted broad attention because of their novel properties due to the intramolecular interaction between the metal atom and the fullerene cage. New electronic properties, such as the low oxidation and reduction potentials, induced by the interaction would allow new application of fullerenes. Reversible addition reaction is useful method for separation of fullerenes and protection of their reactive sites. Recently, we have reported the reversible and regioselective addition reaction of La@C82 with cyclopentadiene (Cp). This retro-reaction proceeds much faster than that of C60Cp. In this context, it is important to retard the retro-reaction of La@C82Cp. It has been reported that an adduct of C60 and pentamethylcyclopentadiene (Cp*) is less prone to undergo the retro-reaction than C60Cp. Herein, we report the reversible addition reaction of La@C82 with Cp* and the stability of its adduct.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 57 (0), 43-43, 2007
The Society of Physical Organic Chemistry, Japan
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Details 詳細情報について
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- CRID
- 1390282680532127232
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- NII Article ID
- 130004646467
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed