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Theoretical Studies on the Structure of Supercritical Fluids

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Other Title
  • 超臨界流体の構造に関する理論的研究

Abstract

We carried out isobaric-isothermal Monte Carlo simulationsto study Lennard-Jones supercritical fluids.The static structure factors are calculatedfrom the coordinates of the particles,and investigated by use of the Ornstein-Zernike(OZ) type function.It is found that the ridge of S(0) does not coincide with that of guzaiand lies in the lower-pressure regionin the pressure-temperature phase diagram.This result confirms the recent experiments.We interpret them qualitatively from a microscopic point of view,and discuss the characteristics of supercritical fluids.

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Details

  • CRID
    1390282680570783104
  • NII Article ID
    130004603543
  • DOI
    10.11345/japannctam.54.0.55.0
  • Data Source
    • JaLC
    • CiNii Articles
    • KAKEN
  • Abstract License Flag
    Disallowed

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