4-ヨードフェノキシ酢酸-オキソン系を用いるフェノール類の触媒的酸化反応
書誌事項
- タイトル別名
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- Catalytic Hypervalent Iodine Oxidations of Phenols Using 4-Iodophenoxyacetic Acid-Oxone System
説明
We report here novel hypervalent iodine oxidations of phenols using a catalytic amount of 4-iodophenoxyacetic acid and an equimolar amount or an excess of Oxone (2KHSO5•KHSO4•K2SO4) as a co-oxidant. <BR> This oxidation system has the following features. The first is that reaction proceeds under mild conditions. The second is that Oxone is an inorganic, water-soluble, commercially available, and inexpensive with low toxicity. The third is that solubility of the catalyst in alkaline solution facilitates its recovery.
収録刊行物
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- 反応と合成の進歩シンポジウム 発表要旨概要
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反応と合成の進歩シンポジウム 発表要旨概要 35 (0), 88-88, 2009
日本薬学会化学系薬学部会
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詳細情報 詳細情報について
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- CRID
- 1390282680612110464
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- NII論文ID
- 130006997887
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可