4-ヨードフェノキシ酢酸-オキソン系を用いるフェノール類の触媒的酸化反応

書誌事項

タイトル別名
  • Catalytic Hypervalent Iodine Oxidations of Phenols Using 4-Iodophenoxyacetic Acid-Oxone System

説明

We report here novel hypervalent iodine oxidations of phenols using a catalytic amount of 4-iodophenoxyacetic acid and an equimolar amount or an excess of Oxone (2KHSO5•KHSO4•K2SO4) as a co-oxidant. <BR> This oxidation system has the following features. The first is that reaction proceeds under mild conditions. The second is that Oxone is an inorganic, water-soluble, commercially available, and inexpensive with low toxicity. The third is that solubility of the catalyst in alkaline solution facilitates its recovery.

収録刊行物

詳細情報 詳細情報について

  • CRID
    1390282680612110464
  • NII論文ID
    130006997887
  • DOI
    10.14895/hannou.35.0.88.0
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

問題の指摘

ページトップへ