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- KAWABATA Toshiharu
- Department of Biomedical Research on Food, National Institute of Health
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- NAKAMURA Masamichi
- Kanagawa Prefectural Public Health Institute
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- MATSUI Masami
- Tokyo Research Laboratory, Shimadzu Seisakusho, Ltd.
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- ISHIBASHI Tohru
- Department of Biomedical Research on Food, National Institute of Health
Bibliographic Information
- Other Title
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- 水産加工食品中のN-ニトロサミンに関する研究-I
- ガス クロマトグラフィー オヨビ ハクソウ クロマトグラフィー ニ ヨル テイセイ オヨビ テイリョウホウ ノ ケントウ
- Determination of trace quantities of volatile N-nitrosamines by thin-layer and gas-liquid chromatography
- ガスクロマトグラフィーおよび薄層クロマトグラフィーによる定性および定量法の検討
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Description
The assessment of potential health hazards due to N-nitrosamines requires reliable analytical method(s) of identification and concentration of such compounds in vulnerable foodstuffs, such as nitride treated fishery products, e.g. fish-sausage and ham, and salted salmon roe. Basic studies were conducted on the determination of trace quantities of volatile N-nitrosamines by thin-layer (TLC) and gas-liquid chromatography (GLC). Results obtained may be summarized as follows:<br>1. The maximum rate of coloring of dimethylnitrosamine (DMNA) on a TLC plate was obtained by ultraviolet irradiation light (λmax=253.7 nm) using a dose of about 15, 000μW/cm2.<br>2. Rf values for 8 N-nitrosamines on TLC (Silicagel G plates) were determined using 3 different solvent systems.<br>3. Resolutions and sensitivities of a gas chromatograph equipped with an alkali thermoionic detector (KBr crystal) for 8 N-nitrosamines were compared with 4 types of columns. Both Chromosorb W-PEG 6, 000 and Chromosorb W-Versamid 900 were found to be suitable for the qualitative and quantitative analyses of trace amount of N-nitrosamines.<br>4. The formation of DMNA in the nitrite treated Alaska pollack roe sample has been confirmed by a gas-liquid chromatograph-mass spectrometer.
Journal
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- NIPPON SUISAN GAKKAISHI
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NIPPON SUISAN GAKKAISHI 40 (1), 79-85, 1974
The Japanese Society of Fisheries Science
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Keywords
Details 詳細情報について
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- CRID
- 1390282681390853760
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- NII Article ID
- 130000919761
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- NII Book ID
- AN00193422
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- COI
- 1:CAS:528:DyaE2cXhtF2ht7Y%3D
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- ISSN
- 1349998X
- 00215392
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- NDL BIB ID
- 7619360
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed