Radical Polymerization of Styrene, <I>p</I>-Methylstyrene and <I>p</I>-Methoxystyrene

DOI
  • Kinoshita Masayoshi
    Department of Applied Chemistry, Faculty of Engineering, Osaka City University
  • Imoto Minoru
    Department of Applied Chemistry, Faculty of Engineering, Osaka City University

Bibliographic Information

Other Title
  • スチレン, メチルスチレンおよびメトキシスチレンのラジカル重合

Description

To know the relationship between substituents of styrene derivatives and their reactivity in propagation and termination reactions, the elementary reactions in the radical polymerization of p-substituted styrenes were analyzed. In measuring radical life times we used the most proper rotating sector method.<BR>Initiation reaction rate was determined by inhibitor method and in this paper DPPH and benzoquinone were chosen as inhibitor. Obtained kp values of styrene, p-methylstyrene and p-methoxystyrene were 106, 84 and 71, and 2kt values were 10.8×107, 6.6×107 and 3.3×107l/mol·sec, respectively.

Journal

  • Kobunshi Kagaku

    Kobunshi Kagaku 20 (216), 231-236, 1963

    The Society of Polymer Science, Japan

Details 詳細情報について

  • CRID
    1390282681496785152
  • NII Article ID
    130004032382
  • DOI
    10.1295/koron1944.20.231
  • ISSN
    18848079
    00232556
  • Text Lang
    ja
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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