Non-enzymatic hydroxylation of benzene with polymeric supports.

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Other Title
  • 高分子担体を用いるベンゼンの非酵素的水酸化反応
  • コウブンシ タンタイ オ モチイル ベンゼン ノ ヒ コウソテキ スイサンカ

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Description

Non-enzymatic heterogeneous hydroxylation of benzene into phenol in the presence of L-ascorbic acid and oxygen was studied. We used of solid polymeric catalysts such as poly (methyl methacrylate) (PMMA), poly (methyl vinyl ketone) (PMVK), and ion-exchange or chelate resins that carry supported Fe2+ or Cu+ ion to mimick the hydroxylase. The reaction was strongly affected by the polymeric catalyst systems. When the hydroxylation was repeated three times in the same batch reactors, the phenol yields with the PMMA and PMVK catalysts were 20 times higher than in their absence.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 47 (8), 691-693, 1990

    The Society of Polymer Science, Japan

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