高分子担体を用いるベンゼンの非酵素的水酸化反応

DOI Web Site

書誌事項

タイトル別名
  • Non-enzymatic hydroxylation of benzene with polymeric supports.
  • コウブンシ タンタイ オ モチイル ベンゼン ノ ヒ コウソテキ スイサンカ

この論文をさがす

説明

Non-enzymatic heterogeneous hydroxylation of benzene into phenol in the presence of L-ascorbic acid and oxygen was studied. We used of solid polymeric catalysts such as poly (methyl methacrylate) (PMMA), poly (methyl vinyl ketone) (PMVK), and ion-exchange or chelate resins that carry supported Fe2+ or Cu+ ion to mimick the hydroxylase. The reaction was strongly affected by the polymeric catalyst systems. When the hydroxylation was repeated three times in the same batch reactors, the phenol yields with the PMMA and PMVK catalysts were 20 times higher than in their absence.

収録刊行物

  • 高分子論文集

    高分子論文集 47 (8), 691-693, 1990

    公益社団法人 高分子学会

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ