ビスマレイミドとテトラカルボン酸ジイミドとの反応によるポリイミドの合成

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書誌事項

タイトル別名
  • New Synthesis of Aromatic-Aliphatic Copolyimides by the Polyaddition Reaction of Tetracarboxylic Acid Diimides with Bismaleimides
  • ビスマレイミド ト テトラカルボンサン ジイミド ト ノ ハンノウ ニヨル ポ
公開日
1975
DOI
  • 10.1295/koron.32.569
公開者
公益社団法人 高分子学会

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説明

Aromatic-aliphatic copolyimides were synthesized by a new procedure, i. e., the polyaddition reaction of tetracarboxylic acid diimides with bismaleimides. In these polyaddition reactions, a small amount of m-cresol acts as a catalyst as well as a radical inhibitor for bismaleimides. Their chemical structures were determined by elemental analyses and from IR spectrum of model compound, i. e., N-phenyl-2-phthalimidosuccinimide. Films can be cast from their solutions in polar solvent such as dimethylformamide, but they were not flexible. In comparison with all aromatic polyimides, it was observed that aromatic-aliphatic copolyimides have less thermal stability.

収録刊行物

  • 高分子論文集

    高分子論文集 32 (10), 569-572, 1975

    公益社団法人 高分子学会

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