書誌事項
- タイトル別名
-
- SYNTHESIS AND CHARACTERIZATION OF BLOCK COPOLYMERS BEARING WITH TEMPO
この論文をさがす
抄録
Anionic block copolymerization of 4-methacryloyloxy-2,2,6,6-tetramethylpiperidin-1-oxyl (TEMA) with 2-diethylaminoethyl methacrylate (DEAEMA) was carried out in THF at -78°C in the presence of LiCl. In addition, the resulting copolymer were reacted with C_8 F_17 COOH in order to ntroduce the ionic bond-formed perfluorooctyl group at PDEAEMA segment. The resulting copolymers always possessed controlled molecular weights and rather narrow molecular weight distributions. The characteristic signal for TEMPO radical was observed in ESR spectra of the block copolymers. These results clearly showed the coexistence of TEMPO radical with carbanionic species during the reactions. The redox potential of the copolymers was studied by a cyclic voltammetry.
収録刊行物
-
- 法政大学大学院紀要. 理工学・工学研究科編
-
法政大学大学院紀要. 理工学・工学研究科編 57 1-2, 2016-03-24
法政大学大学院理工学・工学研究科
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390290699807626752
-
- NII論文ID
- 120005860266
-
- NII書誌ID
- AA12677220
-
- HANDLE
- 10114/12724
-
- ISSN
- 21879923
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- IRDB
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用可