Creation of Transition Metal Catalysts with Substrate Recognition Moiety and Development of Regioselective and Substrate Specific Reactions

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  • 基質認識部位をもつ遷移金属触媒の創製と位置選択的，基質特異的な炭素-水素結合変換反応の開発

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<p>Regiocontrol is very important to obtain the desired products efficiently in synthetic organic chemistry. Because there are many C-H bonds with similar reactivities in organic molecules, it was difficult to promote regioselective C-H transformations without using directing groups. In this account, I describe a new strategy to control regioselectivities in C-H transformations using noncovalent interactions, such as hydrogen bond and Lewis acid-base interaction, between the catalyst and the substrate. As a result, highly regioselective C-H transformations have been achieved. By using the catalytic system, the rate of the C-H transformation was accelerated and the yield of the product was improved dramatically. In addition, the substrate and functional group specificities were expressed.</p>

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