基質認識部位をもつ遷移金属触媒の創製と位置選択的，基質特異的な炭素-水素結合変換反応の開発

DOI Web Site 被引用文献2件 参考文献39件

書誌事項

タイトル別名
  • Creation of Transition Metal Catalysts with Substrate Recognition Moiety and Development of Regioselective and Substrate Specific Reactions

説明

<p>Regiocontrol is very important to obtain the desired products efficiently in synthetic organic chemistry. Because there are many C-H bonds with similar reactivities in organic molecules, it was difficult to promote regioselective C-H transformations without using directing groups. In this account, I describe a new strategy to control regioselectivities in C-H transformations using noncovalent interactions, such as hydrogen bond and Lewis acid-base interaction, between the catalyst and the substrate. As a result, highly regioselective C-H transformations have been achieved. By using the catalytic system, the rate of the C-H transformation was accelerated and the yield of the product was improved dramatically. In addition, the substrate and functional group specificities were expressed.</p>

収録刊行物

被引用文献 (2)*注記

もっと見る

参考文献 (39)*注記

もっと見る

関連プロジェクト

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ