液晶性を示す含フッ素安息香酸フェニル誘導体で形成したイオンゲルの熱力学特性およびレオロジー特性
書誌事項
- タイトル別名
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- Thermodynamic and Rheological Properties of Ionic Gels Formed by Fluorine-containing Phenyl Benzoate Derivatives That Exhibit Liquid Crystallinity
抄録
<p>In our previous work, it was found that some rod-shaped low molecular compounds containing perfluoroalkyl group at a terminal position exhibited smectic A phase in bulk state and gelated several organic solvents and/or ionic liquids. In this work, two types of fluorine-containing phenyl benzoate derivatives which changed the orientation of ester group were synthesized, and it was considered that the correlation between liquid crystallinity and gelation with [BMIM][TFSA] from the thermodynamic properties, microscope observation, and rheological properties. As the results of them, the 5wt% gels formed by {4-[2-(perfluorohexyl)]ethylsulfanyl}phenyl 4-(octyloxy)benzoate exhibited thixotropy and observed micelle-like texture by polarized microscope.</p>
収録刊行物
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- 日本液晶学会討論会講演予稿集
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日本液晶学会討論会講演予稿集 2022 (0), PC13-, 2022
一般社団法人 日本液晶学会
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詳細情報 詳細情報について
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- CRID
- 1390296288050912000
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- ISSN
- 24325988
- 18803490
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
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- 抄録ライセンスフラグ
- 使用不可