Raman Spectroscopic Study of Ionic Association in Molten LaCl<sub>3</sub> and Molten CsCl-NaCl Mixtures

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  • Raman Spectroscopic Study of Ionic Association in Molten LaCl3 and Molten CsCl-NaCl Mixtures

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Abstract

<p>The structures of molten LaCl3 and molten CsCl-NaCl mixtures were studied by Raman spectroscopy. Ionic association in these melts was discussed according to the information of vibrational modes. Complex species of the octahedral type, LaCl63−, was formed in the melt and no association was observed in the molten CsCl-NaCl system.</p>

Journal

  • Electrochemistry

    Electrochemistry 73 (11), 936-938, 2005-11-05

    The Electrochemical Society of Japan

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