Flow Electrosynthesis and Molecular Weight Control of Polyphenylene Deriving from 1,4-Bis(trimethylsilyl)benzene: Effect of a Silyl Substituent on the Coupling Position
-
- NAKAMURA Yuto
- Graduate School of Science and Engineering, Yokohama National University
-
- TANAKA Kenta
- Graduate School of Science and Engineering, Yokohama National University
-
- MATSUMURA Yoshimasa
- Graduate School of Science and Engineering, Yamagata University
-
- ATOBE Mahito
- Graduate School of Science and Engineering, Yokohama National University
Description
<p>In this study, we have demonstrated electrochemical synthesis of polyphenylene (PP) deriving from 1,4-bis(trimethylsilyl)benzene using a flow microreactor. The electrochemical flow microreactor allowed effective synthesis of a soluble PP without its deposition. The molecular weight of PP could be controlled by selecting reaction conditions for the electrochemical polymerization in the microreactor. In addition, the role of trimethylsilyl (TMS) group in this reaction process was clarified by the comparison to the polymerization of unsubstituted benzene.</p>
Journal
-
- Electrochemistry
-
Electrochemistry 88 (4), 336-339, 2020-07-05
The Electrochemical Society of Japan
- Tweet
Details 詳細情報について
-
- CRID
- 1390848250126102016
-
- NII Article ID
- 130007869357
-
- ISSN
- 21862451
- 13443542
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- Crossref
- CiNii Articles
- KAKEN
-
- Abstract License Flag
- Allowed