Flow Electrosynthesis and Molecular Weight Control of Polyphenylene Deriving from 1,4-Bis(trimethylsilyl)benzene: Effect of a Silyl Substituent on the Coupling Position
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- NAKAMURA Yuto
- Graduate School of Science and Engineering, Yokohama National University
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- TANAKA Kenta
- Graduate School of Science and Engineering, Yokohama National University
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- MATSUMURA Yoshimasa
- Graduate School of Science and Engineering, Yamagata University
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- ATOBE Mahito
- Graduate School of Science and Engineering, Yokohama National University
説明
<p>In this study, we have demonstrated electrochemical synthesis of polyphenylene (PP) deriving from 1,4-bis(trimethylsilyl)benzene using a flow microreactor. The electrochemical flow microreactor allowed effective synthesis of a soluble PP without its deposition. The molecular weight of PP could be controlled by selecting reaction conditions for the electrochemical polymerization in the microreactor. In addition, the role of trimethylsilyl (TMS) group in this reaction process was clarified by the comparison to the polymerization of unsubstituted benzene.</p>
収録刊行物
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- Electrochemistry
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Electrochemistry 88 (4), 336-339, 2020-07-05
公益社団法人 電気化学会
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詳細情報 詳細情報について
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- CRID
- 1390848250126102016
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- NII論文ID
- 130007869357
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- ISSN
- 21862451
- 13443542
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用可