Magnesium-Promoted Reductive Silylation and Acylation of Tropone and Tropone Acetal
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<jats:title>Abstract</jats:title> <jats:p>Magnesium-promoted reductive coupling of chlorotrialkylsilanes and tropone or tropone acetal in DMF, followed by oxidation with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone in benzene gives 2-trialkylsilyltropones as the main product, and the reductive coupling of tropone with acid anhydrides under similar reaction conditions yields benzene derivatives after ring contraction.</jats:p>
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 86 (10), 1183-1189, 2013-10
Tokyo : Chemical Society of Japan
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詳細情報 詳細情報について
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- CRID
- 1523388080019030016
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- NII論文ID
- 10031201274
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- NII書誌ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL書誌ID
- 024925307
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- 本文言語コード
- en
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- NDL 雑誌分類
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- ZP1(科学技術--化学・化学工業)
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- データソース種別
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- NDL
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