The [4+2] Cycloaddition of 1,6-Dihydro-2-dimethylamino-4,6,6-trimethylpyrimidine with Acetylenic Compounds(Organic,Chemical)

Search this article

Description

1,6-Dihydro-2-dimethylamino-4,6,6-trimethylpyrimidine reacted with acetylenic compounds containing electron-withdrawing groups to yield 2-dimethylaminopyridine derivatives. When monosubstituted acetylenes were used, 4-unsubstituted pyridines were selectively obtained. The results of MINDO/3 calculations are consistent with this regioselectivity.

Journal

Keywords

Details 詳細情報について

  • CRID
    1570572702348745600
  • NII Article ID
    110006281311
  • NII Book ID
    AA00602100
  • ISSN
    00092363
  • Text Lang
    en
  • Data Source
    • CiNii Articles

Report a problem

Back to top