A new stereoselective synthesis of 2-subsdtituted 1,3-bis(trimethylsilyl)propene derivatives and their conversion to cyclopentane and cyclohexane derivatives

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Abstract Ester 2 on treatment with sodium salt of sulfone or sulfoxide afforded 2-substituted 1,3-bis(trimethylsily)propene 3 in good yield, from which cyclopentane and cyclohexane derivatives bearing a trimethylsilyl group in the molecules were synthesized.

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