Wet Chemical Etching of AlN Single Crystals

<jats:p>Anisotropic chemical etching is an important means for characterizing the polarity and defect density of single crystals. In this letter, we present the results of our studies on the etching of bulk AlN crystals in aqueous potassium hydroxide solution. The nitrogen polarity (0001) basal plane initially etched rapidly, while the aluminum polarity basal plane, and prismatic (1<jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" orientation="portrait" mime-subtype="gif" mimetype="image" position="float" xlink:type="simple" xlink:href="S1092578300000302_eqn01" />00) planes were not etched. The etch rate of the nitrogen polarity basal plane eventually decreased to zero, as the surface became completely covered with hexagonal hillocks which were bounded by {1<jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" orientation="portrait" mime-subtype="gif" mimetype="image" position="float" xlink:type="simple" xlink:href="S1092578300000302_eqn01" />01} planes. The hillock density for the self-seeded AlN crystals studied was typically in the range of 5×10<jats:sup>7</jats:sup><jats:italic>cm</jats:italic><jats:sup>−2</jats:sup> to 10<jats:sup>9</jats:sup><jats:italic>cm</jats:italic><jats:sup>−2</jats:sup>. From our analysis of etched AlN crystals, we infer that freely nucleated crystals predominately have the nitrogen to aluminum direction pointing out from the nucleation surface, that is the ends of the AlN crystals facing the source are aluminum polarity.</jats:p>